The most common commercially available storage options along with some of their key characteristics are shown above [1]. Each of these methods has advantages and disadvantages that are critical considerations for selecting the best storage method for a given system and use case.
Low-to-moderate pressure storage in salt caverns or other compatible underground locations enables large quantities of gaseous hydrogen to be stored for long periods of time. Electrical energy input is required for a blower or compressor to inject the hydrogen and buffer gas underground at the desired storage pressure. This approach relies on the necessary local geology as well as connection to a gaseous distribution system similar to natural gas infrastructures. A hydrogen liquefaction plant can also be sited nearby using the underground hydrogen storage as feedstock after removal of the buffer gas.
Material-based or solid-state storage is a broad category that encompasses methods to store hydrogen in a matrix material via microscale adsorption or chemical absorption. Many materials and methods have been developed, with metal hydrides currently the most common type in commercial use. Thermal energy is generally required for the solid-state storage reaction to occur as adding hydrogen is exothermic requiring cooling, and removal is endothermic with heat addition. Metal hydride systems are generally better suited to stationary applications due to their low mass fraction and should be installed where low-cost process heat and cooling are available or low pressure is especially important. However, newer technologies using lightweight matrix materials such as aerogels may hold promise for some mobility applications.
Compressed gaseous hydrogen storage requires electrical energy to create the high pressures required. Cooling is also needed to bring the gas stream back down to ambient temperature due to the heat of compression. Composite overwrap pressure vessels (COPV) designed to withstand the high pressures are commercially available at 350 or 700 bar. Initial mobility demonstrations with hydrogen often use COPV storage, and for some applications this option is sufficient to meet the system goals. For many mobile applications, however, the volumetric energy density and mass fraction of compressed hydrogen storage is too low to meet performance requirements.
Cryogenic LH2 has nearly double the volumetric storage density of 700 bar compressed hydrogen at ambient temperature, and along with low-pressure storage conditions enables a much higher mass fraction. For this reason, many transportation applications transitioning to hydrogen are storing or planning to store in cryogenic liquid form. The primary electrical energy input required for LH2 storage is the liquefaction process. As previously mentioned, LH2 has been the primary storage and distribution method in the space industry for many decades.
In aviation, H2Fly demonstrated LH2 onboard storage during successful flight testing of their small demonstrator aircraft. ZeroAvia and Airbus have publicly shared their LH2 design plans for new aircraft. Nikola and Hyzon have demonstrated long-range truck routes with LH2, and First Mode has demonstrated hydrogen in a large mining truck. Operational mobility systems using LH2 include Hyundai Rotem trams and marine vessels from multiple companies.
Cryo-compressed hydrogen is another option that has intriguing advantages for some mobile applications. In this supercritical storage state, the hydrogen is compressed at cryogenic temperature resulting in higher potential volumetric density compared to LH2 storage. However, the mass fraction is generally less than LH2 storage systems due to the need for thicker walled vessels to withstand the higher pressures. The U.S. Department of Energy (DOE) has funded development of this technology over many years, and it is now being commercialized by Daimler Truck, Verne, and others. Daimler has also developed a ‘subcooled’ transfer process that can fuel a truck with 80 kilogram of hydrogen in 15 minutes or less without a return vent line resulting in onboard cryo-compressed storage. [2]
